A new version of solar cells created by laboratories at Rice and Pennsylvania State universities could open the door to research on a new class of solar energy devices.
The photovoltaic devices created in a project led by Rice chemical engineer Rafael Verduzco and Penn State chemical engineer Enrique Gomez are based on block copolymers, self-assembling organic materials that arrange themselves into distinct layers.
They easily outperform other cells with polymer compounds as active elements.
While commercial, silicon-based solar cells turn about 20 percent of sunlight into electricity and experimental units top 25 percent, there’s been an undercurrent of research into polymer-based cells that could greatly reduce the cost of solar energy, Verduzco said. The Rice/Penn State cells reach about 3 percent efficiency, but that’s surprisingly better than other labs have achieved using polymer compounds.
“You need two components in a solar cell: one to carry (negative) electrons, the other to carry positive charges,” Verduzco said. The imbalance between the two prompted by the input of energy – sunlight – creates useful current.
Since the mid-1980s, researchers have experimented with stacking or mixing polymer components with limited success, Verduzco said. Later polymer/fullerene mixtures topped 10 percent efficiency, but the fullerenes – in this case, enhanced C-60 buckyballs – are difficult to work with, he said.
The Rice lab discovered a block copolymer — P3HT-b-PFTBT — that separates into bands that are about 16 nanometers wide. More interesting to the researchers was the polymers’ natural tendency to form bands perpendicular to the glass. The copolymer was created in the presence of a glass/indium tin oxide (ITO) top layer at a modest 165 degrees Celsius.
With a layer of aluminum on the other side of the device constructed by the Penn State team, the polymer bands stretched from the top to bottom electrodes and provided a clear path for electrons to flow.
“On paper, block copolymers are excellent candidates for organic solar cells, but no one has been able to get very good photovoltaic performance using block copolymers,” Verduzco said. “We didn’t give up on the idea of block copolymers because there’s really only been a handful of these types of solar cells previously tested. We thought getting good performance using block copolymers was possible if we designed the right materials and fabricated the solar cells under the right conditions.”